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Combining multiples

In each of these questions, positive integers should be taken to include 0.
1. What is the largest number that cannot be written in the form \(3a+5b\), where \(a\) and \(b\) are positive integers?
2. What is the largest number that cannot be written in the form \(3a+7b\), where \(a\) and \(b\) are positive integers?
3. What is the largest number that cannot be written in the form \(10a+11b\), where \(a\) and \(b\) are positive integers?
4. Given \(n\) and \(m\), what is the largest number that cannot be written in the form \(na+mb\), where \(a\) and \(b\) are positive integers?

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